衡水市空气主要污染物体积质量的时间分布特征

利用衡水市环境监测站2005—2007年度大气例行检测的数据，对衡水市大气中主要污染物SO^2、NO^2、PM10体积质量值的逐日数据进行统计分析，得出了衡水市空气污染的现状和时间变化规律：（1）污染物体积质量值的月变化曲线呈槽型分布，非取暖期的空气状况明显好于取暖期，取暖期SO^2平均体积质量是非取暖期的2．45倍；（2）污染物体积质量值的日变化曲线基本为两高两低型，其中取暖期污染指数早晨出现极高值的时间比非取暖期明显偏晚；（3）污染物体积质量值的年变化表明了SO^2的体积质量在降低，而NO^2的体积质量却有了小幅增长。     

Pollution characteristics of ambient volatile organic compounds (VOCs) in the southeast coastal cities of China

With the rapid urbanization, the southeast coastal cities of China are facing increasing air pollution in the past decades. Large emissions of VOCs from vehicles and petrochemical factories have contributed greatly to the local air quality deterioration. Investigating the pollution characteristics of VOCs is of great significance to the environmental risk assessment and air quality improvement. Ambient VOC samples were collected simultaneously from nine coastal cities of southeast China using the Tedlar bags, and were subsequently preprocessed and analyzed using a cryogenic preconcentrator and a gas chromatography–mass spectrometry system, respectively. VOC compositions, spatial distributions, seasonal variations and ozone formation potentials (OPFs) were discussed. Results showed that methylene chloride, toluene, isopropyl alcohol and n-hexane were most abundant species, and oxygenated compounds, aromatics and halogenated hydrocarbons were most abundant chemical classes (62.5–95.6 % of TVOCs). Both industrial and vehicular exhausts might contribute greatly to the VOC emissions. The VOC levels in the southeast coastal cities of China were sufficiently high (e.g., 6.5 μg?m^?3 for benzene) to pose a health risk to local people. A more serious pollution state was found in the southern cities of the study region, while higher VOC levels were usually observed in winter. The B/T ratio (0.26?±?0.09) was lower than the typical ratio (ca. 0.6) for roadside samples, while the B/E (1.6–7.6) and T/E (7.2–26.8) ratios were higher than other cities around the world, which indicated a unique emission profile in the study region. Besides, analysis on ozone formation potentials (OFPs) indicated that toluene was the most important species in ozone production with the accountabilities for total OFPs of 22.6 to 59.6 %.     

树脂吸附-Fenton 试剂氧化法预处理炼油碱渣废水

采用树脂吸附-Fenton 试剂氧化组合工艺对某炼油企业炼油碱渣废水进行预处理.实验确定的最佳工艺条件为:3 种树脂串联吸附,废水流量0.33 mL/ min,H2O2加入量0.20 mol / L,n（H2O2）1 n（Fe2 +）= 12,Fenton 试剂氧化进水pH 3,Fenton 试剂氧化反应时间120 m...     

水平潜流人工湿地在不同水力负荷下的水力效率及可视化分析

构建水平潜流人工湿地装置,通过NaCl示踪脉冲实验,得到不同水力负荷条件下的水力停留时间分布密度曲线,根据不同停留时间的关系计算相对水力效率,并利用染料,进行不同水力负荷下的可视化示踪实验,通过MATLAB处理得到高对比度的流态图像。观察"死区"分布,计算"死区"相对面积用以表征其水力效率。结果表明,湿地装置进水水力负荷较高或较低时,水力效率均较低,且水力负荷较大时更明显;水力分布散度(σ2θ)的大小会对水平潜流人工湿地水力效率造成较大影响;在不同水力负荷下,采用水力学效能(λ)所得到的排序结果相比短路值(s)和有效体积比(e)更能代表实际水平潜流人工湿地的水力效率。     

Evaluation of airborne particulate matter and metals data in personal,indoor and outdoor environments using ED-XRF and ICP-MS and co-located duplicate samples

Factors and sources affecting measurement uncertainty associated with monitoring metals in airborne particulate matter (PM) were investigated as part of the Windsor, Ontario Exposure Assessment Study (WOEAS). The assessment was made using co-located duplicate samples and a comparison of two analytical approaches: ED-XRF and ICP-MS. Sampling variability was estimated using relative percent difference (RPD) of co-located duplicate samples. The comparison of ICP-MS and ED-XRF results yields very good correlations (R² ≥ 0.7) for elements present at concentrations that pass both ICP-MS and ED-XRF detection limits (e.g. Fe, Mn, Zn, Pb and Cu). PM concentration ranges (median, sample number) of 24-h indoor PM₁₀ and personal PM₁₀ filters, and outdoor PM_2.5 filters were determined to be 2.2–40.7 (11.0, n = 48) μg m^?3, 8.0–48.3 (11.9, n = 48) μg m^?3, and 17.1–42.3 (21.6, n = 18) μg m^?3, respectively. The gravimetric analytical results reveal that the variations in PM mass measurements for same-day sampling are insignificant compared to temporal or spatial variations: 92%, 100% and 96% of indoor, outdoor and personal duplicate samples, respectively, pass the quality criteria (RPD ≤ 20%). Uncertainties associated with ED-XRF elemental measurements of S, Ca, Mn, Fe and Zn for 24-h filter samples are low: 78%–100% of the duplicate samples passed the quality criteria. In the case of 24-h filter samples using ICP-MS, more elements passed the quality criteria due to the lower detection limits. These were: Li, Na, K, Ca, Si, Al, V, Fe, Mn, Co, Cu, Mo, Ag, Zn, Pb, As, Mg, Sb, Sn, Sr, Th, Ti, Tl, and U. Low air concentrations of metals (near or below instrumental detection limits) and/or inadvertent introduction of metal contamination are the main causes for excluding elements based on the pass/fail criteria. Uncertainty associated with elemental measurements must be assessed on an element-by-element basis.     

活性碳纤维改性技术研究进展

介绍了活性碳纤维(ACF)的孔结构及表面官能团,综述了国内外ACF改性技术的研究现状.ACF的改性主要包括孔结构调控和表面化学改性,表面化学改性包括氧化还原法、表面负载法、浸渍法、热处理法、远程等离子体处理法、微波辐照法等,也可将多种方法结合来对ACF进行改性,以改善和提高ACF的吸附性能.在总结现有研究的基础上,对ACF改性技术发展趋势进行了展望.     

重金属元素在冻土与融土中迁移的对比试验

随着寒区经济的发展,冻土地区的矿山开采活动不断加剧,随之产生的重金属污染问题也越来越严重.冻土地区生态环境脆弱,一旦受到破坏就很难恢复.针对此问题,室内模拟了尾矿矿渣在冻土与融土中的填埋及其对填埋场周边土体的影响,通过检测填埋场各处土壤的温度、含水量以及重金属元素的含量,发现温度和水分对重金属元素的迁移影响很大.土壤温度越低,重金属元素的迁移越慢;在温度梯度的作用下,重金属元素均随着水分从土体的暖端向冷端迁徙并聚集于冻结锋面.重金属元素在冻土中的迁移比融土中慢,表明冻土环境不利于重金属元素的迁移.在土壤质地、温度和含水量等相同的情况下,Zn的迁移性较强,Pb和Cu的迁移性相对较弱.     

炭黑工业烟气余热的回收及利用

对油炉法炭黑生产过程烟气的来源，组成，发生量，特性作了介绍，着重研究了炭黑烟气余热的加收及利用。结果表明，采用余热锅炉串联多级空气预热器，是目前我国炭黑烟气余热回收及利用的最佳方法，采用这种方法，不仅可将高温炭黑烟气的余热量最大限度地回收及利用，同时可满足炭黑收集及烟气净化系统设备对炭黑烟气温度的要求，采用该法，炭黑烟气余热利用率可提高２０％以上，经济效益十分可观。     

孤岛油区外排采油污水生化处理技术的研究

针对孤岛污水矿化度高,Cl-含量高,油含量和COD含量严重超标的现象,采取微生物接触氧化工艺进行外排采油污水治理的工艺研究。在处理过程中首先对菌种进行了严格的筛选和培养,然后在室内进行了模拟试验,最后在现场进行了中试。目前已根据中试结果,对孤岛污水原有的污水池进行了改造,设置了隔油池、气浮池、接触氧化池和沉淀池四个部分,经过一年的运行,成功地实现了污水的达标排放。     

违纪解除劳动合同法律要件分析

王某2006年1月1日与某公司签订了劳动合同,合同期限至2008年1月1日,任该公司部门主管.2007年3月20日，该公司作出了《解除劳动合同通知书》，其内容为：“王某，你与本单位2006年1月1日签订了两年期限的劳动合同，因严重失职、玩忽职守，根据《劳动法》第7条规定，决定从2007年3月20日起解除劳动合同，无经济补偿金。”在王某仍然上班的情况下，该公司将通知书在公告栏内张贴。王某对此处理决定不服，于2007年3月21日申请劳动争议仲裁，请求撤销该处理决定。